Hi Marinersfan,
you can not win a shootout in regulation time. If you bet Germany ML they have to win in regulation time (90 min), otherwise it's a loss. If you want to include overtime and shootout in your bet you have to take the bet "Germany to advance next round", but the odds are of course lower. All moneline bets are for regulation time (90 min) and of course you can also also bet draw for regulation time.
cheers,
colton